| # | Clue | Answer As Given | Value | Round | Category | Air Date | Show |
|---|---|---|---|---|---|---|---|
| Rio de Janeiro, Buenos Aires, Asuncion | Rio de Janeiro | $200 | J | NOT A NATIONAL CAPITAL | 2004-01-19 | #4461 | |
| In 1960, Brazil's capital was moved from this city to Brasilia | Rio de Janeiro | $200 | DJ | FORMER CAPITALS | 1986-09-15 | #461 | |
| Until Brasilia was carved from the wilderness, this was Brazil’s capital | Rio de Janeiro | $100 | J | FORMER CAPITALS | 1984-10-12 | #25 |