| # | Clue | Answer As Given | Value | Round | Category | Air Date | Show |
|---|---|---|---|---|---|---|---|
| The method of working this metal was not mastered until about 1500 B.C. under the Hittites | iron | $500 | J | ARCHAEOLOGY | 1994-09-26 | #2311 | |
| Ochre, a yellow or red oxide of this metal, was used as coloring matter in cave paintings | iron | $500 | J | ARCHAEOLOGY | 1994-03-25 | #2210 |